Rapid phosphorus triester hydrolysis catalyzed by bimetallic tetrabenzimidazole complexes.

نویسندگان

  • Kortney L Klinkel
  • Lauren A Kiemele
  • Douglas L Gin
  • John R Hagadorn
چکیده

Bimetallic complexes based on the binucleating ligand N,N,N',N'-tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane (1L) and its new toluoyl ester derivative (2L) catalyze the hydrolysis of phosphorus triesters at ambient temperature with activities rivalling the fastest known systems.

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عنوان ژورنال:
  • Chemical communications

دوره 27  شماره 

صفحات  -

تاریخ انتشار 2006